I am almost certain it was the socks, especially if you say that they slid down and your shins were rubbing directly against the liner of the boot.
I never had problems with blisters in my boots until I wore them with regular socks while helping my kid learn to ski on the magic carpet run. I didn't even ride but just walked up and down the hill for a few hours. I had blisters on both feet and I am certain that it was because I was wearing normal socks.
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